8-Hydroxyquinolin-1-ium nitrate

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8-Hy­droxy­quinolin-1-ium nitrate

In the title salt, C(9)H(8)NO(+)·NO(3) (-), the quinoline ring system is essentially planar with a maximum deviation of 0.043 (1) Å. In the crystal, an R(2) (2)(7) ring motif is formed by inter-molecular N-H⋯O and C-H⋯O hydrogen bonds between the cation and the anion. In addition, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds link the two ions, generating an R(2) (2)(8) ring motif. These sets ...

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A proton is transferred from the nitric acid to the N atom of 2-cyano-quinoline during crystallization, resulting in the formation of the title salt, C(10)H(7)N(2) (+)·NO(3) (-). The quinolinium ring system is approximately planar, with a maximum deviation of 0.013 (3) Å. In the crystal, a very asymmetric bifurcated N-H⋯(O,O) hydrogen bond to two O atoms of an adjacent nitrate anion occurs, gen...

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In the title compound, C(26)H(29)N(2) (+)·NO(3) (-), the dihedral angle formed by the phenyl rings of the benzhydryl group is 66.18 (9)°. Crystal cohesion is enforced by cation-anion C-H⋯O and N-H⋯O hydrogen bonds.

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In the crystal structure of the title salt hydrate, C9H8NO(+)·HSO4 (-)·H2O, the quinoline N-H atoms are hydrogen bonded to the bis-ulfate anions. The bis-ulfate anions and water mol-ecules are linked together by O-H⋯O hydrogen-bonding inter-actions. The cations and anions form separate layers alternating along the c axis, which are linked by N-H⋯O and O-H⋯O hydrogen bonds into a two-dimensional...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810039395